Pack the sliced onions tightly into a clean pint jar.
Combine the vinegar, water, sugar, salt, bay leaf and peppercorns in a small saucepan and bring to a simmer over medium heat, stirring until the sugar and salt dissolve, about 3 minutes.
Pour the hot brine over the onions, making sure they're fully submerged.
Let the jar cool at room temperature for 1 hour, uncovered.
Cover and refrigerate at least 1 hour before serving, or up to 2 weeks, until the onions turn bright pink all the way through.
Good to Know
Make this up to 2 weeks ahead; it's one less thing on the day-of list.